VANADIUM OXIDES AND OTHER VANADIUM COMPOUNDS
By Jim Shook 3/27/2014
Four Principle Oxides of Vanadium: VO, V2O3, VO2 & V2O5
VO = VANADIUM OXIDE = VANADIUM(II) OXIDE = VANADIUM MONOXIDE
V2O3 = VANADIUM OXIDE = VANADIUM(III) OXIDE = DIVANADIUM TRIOXIDE
VO2 = VANADIUM OXIDE = VANADIUM(IV) OXIDE = VANADIUM DIOXIDE
V2O5 = VANADIUM OXIDE = VANADIUM(V) OXIDE = DIVANADIUM PENTOXIDE
A) Phases of V(n)O(2n+1) B) Phases of V(n)O(2n-1)
n V(n) O(2n+1) Combined n V(n) O(2n-1) Combined
------------------------------- -----------------------------
1 V1 O3 VO3- (ion) 1 V1 O1 VO
2 V2 O5 V2O5 2 V2 O3 V2O3
3 V3 O7 V3O7 3 V3 O5 V3O5
4 V4 O9 V4O9 4 V4 O7 V4O7
5 V5 O11 V5O11 5 V5 O9 V5O9
6 V6 O13 V6O13 6 V6 O11 V6O11
7 V7 O13 V7O13
8 V8 O15 V8O15
A third series is V(n)O(2n) resulting in VO2, V2O4, V3O6 etc. However,
these are all multiples of VO2. VO2 is the empirical formula for these.
Although a few sources specifically reference V2O4.
15 Different Oxides Of Vanadium with 55 Different Names:
CHEMICAL NAME CHEMICAL FORMULA MOLAR MASS
4
VANADIUM OXIDE VO 66.940877
VANADIUM MONOXIDE VO 66.940877
VANADIUM(II) OXIDE VO 66.940877
VANADIUM(II) MONOXIDE VO 66.940877
4
VANADIUM OXIDE VO2 82.940282
VANADIUM DIOXIDE VO2 82.940282
VANADIUM(IV) OXIDE VO2 82.940282
VANADIUM(IV) DIOXIDE VO2 82.940282
9
VANADIUM OXIDE V2O3 149.881158
VANADIUM TRIOXIDE V2O3 149.881158
VANADIUM(III) OXIDE V2O3 149.881158
VANADIUM(III) TRIOXIDE V2O3 149.881158
DIVANADIUM OXIDE V2O3 149.881158
DIVANADIUM TRIOXIDE V2O3 149.881158
DIVANADIUM(III) OXIDE V2O3 149.881158
DIVANADIUM(III) TRIOXIDE V2O3 149.881158
VANADIUM SESQUIOXIDE V2O3 149.881158
8
VANADIUM OXIDE V2O5 181.879968
VANADIUM PENTOXIDE V2O5 181.879968
VANADIUM(V) OXIDE V2O5 181.879968
VANADIUM(V) PENTOXIDE V2O5 181.879968
DIVANADIUM OXIDE V2O5 181.879968
DIVANADIUM PENTOXIDE V2O5 181.879968
DIVANADIUM(V) OXIDE V2O5 181.879968
DIVANADIUM(V) PENTOXIDE V2O5 181.879968
8
VANADIUM OXIDE V2O4 165.880563
VANADIUM TETRAOXIDE V2O4 165.880563
VANADIUM(IV) OXIDE V2O4 165.880563
VANADIUM(IV) TETRAOXIDE V2O4 165.880563
DIVANADIUM OXIDE V2O4 165.880563
DIVANADIUM TETRAOXIDE V2O4 165.880563
DIVANADIUM(IV) OXIDE V2O4 165.880563
DIVANADIUM(IV) TETRAOXIDE V2O4 165.880563
4
VANADIUM OXIDE V3O5 232.821440
VANADIUM PENTOXIDE V3O5 232.821440
TRIVANADIUM OXIDE V3O5 232.821440
TRIVANADIUM PENTOXIDE V3O5 232.821440
18
VANADIUM OXIDE V3O7 264.820250
TRIVANADIUM HEPTAOXIDE V3O7 264.820250
VANADIUM OXIDE V4O9 347.760531
TETRAVANADIUM NONAOXIDE V4O9 347.760531
VANADIUM OXIDE V5O11 430.700813
PENTAVANADIUM UNDECAOXIDE V5O11 430.700813
VANADIUM OXIDE V6O13 513.641094
HEXAVANADIUM TRIDECAOXIDE V6O13 513.641094
VANADIUM OXIDE V4O7 315.761721
TETRAVANADIUM SEPTOXIDE V4O7 315.761721
VANADIUM OXIDE V5O9 398.702003
PENTAVANADIUM NONAOXIDE V5O9 398.702003
VANADIUM OXIDE V6O11 481.642284
HEXAVANADIUM UNDECAOXIDE V6O11 481.642284
VANADIUM OXIDE V7O13 564.582566
HEPTAVANADIUM TRIDECAOXIDE V7O13 564.582566
VANADIUM OXIDE V8O15 647.522848
OCTAVANADIUM QUINDECAOXIDE V8O15 647.522848
50 other Vanadium Compounds:
AMMONIUM VANADIUM OXIDE NH4VO3 116.978193
DIVANADIUM MONOHYDRIDE V2H 102.890884
DIVANADIUM TRISULPHIDE V2S3 198.081197
SODIUM VANADIUM TETRAOXIDE Na3VO4 183.908400
SODIUM VANADIUM TRIOXIDE NaVO3 121.929456
TRIVANADIUM SILICIDE V3Si 180.909800
VANADIUM DIBORIDE VB2 72.563528
VANADIUM DIBROMIDE VBr2 210.748529
VANADIUM DICARBIDE VC2 74.962943
VANADIUM DICHLORIDE VCl2 121.846548
VANADIUM DICHLORIDE OXIDE VCl2O 137.845953
VANADIUM DIFLUORIDE VF2 88.938278
VANADIUM DIIODIDE VI2 304.750408
VANADIUM DIMER V2 101.882943
VANADIUM DISELENIDE VSe2 208.860249
VANADIUM DISULPHIDE VS2 115.073641
VANADIUM DITELLURIDE VTe2 306.147722
VANADIUM HEXACARBONYL V(CO)6 219.002317
VANADIUM MONOCARBIDE VC 62.952208
VANADIUM MONOCHLORIDE VCl 86.394010
VANADIUM MONOHYDRIDE VH 51.949412
VANADIUM MONONITRIDE VN 64.948215
VANADIUM MONOPHOSPHIDE VP 81.915233
VANADIUM MONOSULPHIDE VS 83.007556
VANADIUM OXIDE SULPHATE VOSO4 163.004581
VANADIUM TETRAMER V4 203.765887
VANADIUM TRIMER V3 152.824415
VANADIUM TRITHIOPHOSPHITE VPS3 178.113487
VANADIUM(III) ACETYLACETONATE V(C5H7O2)3 348.265696
VANADIUM(III) MONONITRIDE VN 64.948215
VANADIUM(III) TRIBROMIDE VBr3 290.652057
VANADIUM(III) TRICHLORIDE VCl3 157.299086
VANADIUM(III) TRIFLUORIDE VF3 107.936681
VANADIUM(III) TRIHYDROXIDE V(OH)3 101.963509
VANADIUM(III) TRIIODIDE VI3 431.654876
VANADIUM(IV) DICARBONATE V(CO3)2 170.959373
VANADIUM(IV) DISELENIDE VSe2 208.860249
VANADIUM(IV) TETRABROMIDE VBr4 370.555585
VANADIUM(IV) TETRACHLORIDE VCl4 192.751624
VANADIUM(IV) TETRAFLUORIDE VF4 126.935084
VANADIUM(IV) TETRAIODIDE VI4 558.559344
VANADIUM(V) OXIDE PHOSPHATE VOPO4 161.912258
VANADIUM(V) PENTAFLUORIDE VF5 145.933488
VANADIUM(V) TRICHLORIDE OXIDE VCl3O 173.298491
VANADIUM(V) TRIFLUOROOXIDE VF3O 123.936086
VANADYL(IV) ACETYLACETONATE VO(C5H7O2)2 265.157026
VANADYL(IV) SULFATE VOSO4 163.004581
VANADYL(V) PHOSPHATE VOPO4 161.912258
VANADYL(V) TRICHLORIDE VOCl3 173.298491
VANADYL(V) TRIFLUORIDE VOF3 123.936086